Un artículo del grupo portada de Chemistry

The stereoselective synthesis of 1,3-diaminotruxillic acid derivatives has been achieved in high yields and short reaction times. The procedure starts from simple 5(4H)- oxazolones and is based on an efficient combination of C[BOND]H orthopalladation, [2+2]-photocycloaddition on continuous flow microreactors using visible light from LED sources, and hydrogenation to selectively afford the epsilon isomer.

 

Chemistry 2016

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