New papers on the application of triazoles in materials chemistry
A sustainable synthesis of alkenyl-1H-1,2,4-triazoles through the Hiyama reaction is reported.
All compounds are good blue emitters (ΦF up to 0.69) in THF solution, although they exhibit an optical behavior dependent on the substitution. These results were published in ChemPlusChem.
In a second paper published in Chem. Eur. J. the synthesis of a series of 4-aryl-3,5-bis(arylethynyl)aryl-4H-1,2,4-triazoles derivatives is reported and the influence exerted by peripheral substitution on the morphology of the aggregates generated from these 1,2,4-triazoles is investigated by SEM imaging.
Finally a review has been published in Current Org. Chem. in order to emphasize the most important metal-free derivatives bearing 1,2,4-triazole moieties with applications as organic materials.